I was getting errors while trying to use the Rectify tool in Textools, so I did some digging. It looks likes the addon hasn't been fully updated for Blender 5.0 and isn't functional (at least the UV Editing tools.)
Luckily Chunck showed how to do it in vanilla Blender as well; but if anyone has a similar addon that works well or information on Textools I missed feel free to link it :) !
I had this issue but the Blender master zip works for me on 4.5
https://github.com/franMarz/TexTools-Blender?tab=readme-ov-file
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Scroll to the bottom.
Installation
Click the Master link
Just chiming in as well to mention two alternatives, for anyone who is looking.
Lately, I've been using an extension called UniV. I've been pretty happy with it, seems to do everything I need it to and is feature parity with what I've wanted out of Textools! I have also just been introduced to another called Mio3 UV, it looks incredibly robust and I am looking forward to testing it out myself here sometime soon.